Sodium triacetoxyborohydride

Sodium triacetoxyborohydride, also known as sodium triacetoxyhydroborate,
commonly abbreviated STAB, is a white hygroscopic solid that emits hydrogen gas
when hydrolysed in water, which is flammable. It is a milder reducing agent
than sodium borohydride or even sodium cyanoborohydride. Even sodium
cyanoborohydride is a milder reducing agent than sodium borohydride, and is
particularly suitable for the reductive amination of aldehydes and ketones. It
can reduce aldehydes but not most ketones.
Sodium triacetoxyborohydride is a mild reagent that exhibits remarkable
selectivity as a reducing agent. It reduces aldehydes but not ketones; however,
beta-hydroxyketones can be reduced selectively to give 1,3-trans diols.The
steric and the electron-withdrawing effects of the three acetoxy groups
stabilize the boron-hydrogen bond and are responsible for its mild reducing
properties. It can also be used in the reductive alkylation of secondary amines
in aldehyde-bisulfite adducts.
Brand: Soarwin
CAS No.: 56553-60-7
EC Number: 435-580-8
Molecular Formula: C6H10BNaO6
Density: 1.36[at 20°C]
Melting point: 116-120°C (dec.) (lit.)
Boiling point: 111.1°C(Predicted)

Minimum Order: 1 kilograms